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Performance Requirements of High - Low Temperature for Lithium Sub - Batteries in Application Enviro

Lithium sub-batteries, full name lithium - thionyl chloride batteries, lithium thionyl chloride batteries in all the batteries, are a very unique species. Its voltage is 3.6V. The cathode material is thionyl chloride (thionyl chloride), and also the> Lithium-ion batteries are common in consumer electronics, with one of the best energy-to-weight ratios, no memory effect, and a slow loss of charge when not in use. In addition to uses fo electrolyte. This characteristic makes its specific energy very high. Is the highest voltage lithium battery. Storage life can be more than 10 years.


Lithium-thionyl chloride battery cell works: Li / SOCl2 battery to ies are technological evolution from lithium-ion batteries. The primary difference is that the lithium-salt electrolyte is not held in an organic solvent but in a solid polymer composite such as polyethylene oxide or polyacrylonitrile.
The advr lithium as cathode, carbon as a positive, anhydrous lithium tetrachloroaluminate (LiAlCl4) SOCl2 solution as electrolyte, SOCl2 is the cathode active material. LiFePO4-SOCl2 / C negative electrode: 4Li = 4Li + + 4e Positive electrode: 2SOCL2 + 4e = 2SO2 +weight and size benefits of Li-ion but are proven to be far safer in critical situations; coupled with a working life of 1,000 charging cycles, double that of other battery types. 

Operating principles of rechargeable lithium ba salign:justify;"> 3). When recharging, use the battery charger specifically for that purpose.

4). Do not reverse the positive ( + ) and negative ( - ) terminals.

5). Do notf|tY@`|f|ҙ|``|p#f|c`|#f|BO- f|$f|ZRې3f|`|(: 23f|`$f|:)3f| |ja^ t connect the battery to an electrical outlet.

6). Do not discard the battery in fire or heat it.

7). Do not short-circuit the battery by directly connecting the positive ( + `|$f|3o5f|%f|@5f|P%f|Þt{1+p5f|@`|jTNݓ`f|%f|9 w35f|``|7dv=Q%f|f|'n^mf| `|O| ) and negative ( - ) terminal with metal objects such as  wire.             

8). Do not transport or store the battery together with metal objects such as necklaces, hairpinerred to as the delay time and the lowe#`|( ( Xe|j"j"Y"T"S" T" T"g|j"j"s etc.

9). Do not strike or throw the battery.

10).Do not directly solder the battery and pierce the battery with a nail or other incisive

The degree of passivation i 4Cl-2SO (3) Sulfur dioxide battery Total reaction: 4Li + 2SOCl2 4LiCl + S + SO2 SO2 all dissolved in SOCl2, S a large number of precipitation, deposition in the cathode carbon black, LiCl is insoluble. This kind of battery, Li and SOCl2 contact, the reaction occurs as follows: 8Li + 4SOCl2 6LiCl + Li2S2O4 + S2Cl2 or 8Li +3SOCl2 6LiCl + Li2SO3 +2S Because of this reaction, although the Li / SOCl2 battery cathode active material SOCl2 tightly surrounded the negative electrode, but in fact did not happen short circuit phenomenon, this is because the negative electrode surface to form a layer of very thin dense LiCl protective film (primary film), this film has electronic insulation, the ion can wear So as to prevent the external SOCl2 and lithium further reaction, the lithium in SOCl2 electrolyte becomes very stable, with the ambient temperature and battery storage time, the primary film will gradually expand the thickening of the so-called two Sub-film, the battery also has a very good shelf life. 


As a result, Li / SOCl2 battery has a more serious voltage hysteresis phenomenon, the hysteresis of the voltage in a few minutes to restore the peak voltage to 95%. The LiCl film formed on the surface of the LiCl layer can be destroyed by the initial voltage of the LiCl / SOCl2 battery after two years storage at 25 , such as short circuit of the battery or intermittent discharge with large current for several times. restore. The products LiCl (white) and S (yellow) were deposited in the positive carbon black, partially blocking the micropores in the positive electrode. On the one hand, some positive expansion, on the other hand hinder the diffusion of the electrolyte, increasing the concentration of polarization, the battery gradually failure.



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